INFRARED STUDIES OF SULPHUR-CONTAINING ORGANIC DERIVATIVES OF PHOSPHORUS PYROACIDS

Authors
  1. McIvor, R.A.
  2. Grant, G.A.
  3. Hubley, C.E.
Corporate Authors
Defence Research Chemical Labs, Ottawa ONT (CAN)
Abstract
The assignments of several infrared bands of aliphatic phosphorus compounds have been reviewed and extended on the basis of new or improved data. These bands include POP, P - S, PSH, PSR, PH and PCl. Several new assignments are proposed, mainly in the 12 - 24 mu region. Two examples are given of the application of these assignments to the determination of the structure of the thiopyrophosphates. It is shown that all procedures used for preparing monothio-pyrophosphates yield exclusively the thiono isomer.
Report Number
DRCL-203A — Reprint; Previously accessioned as DSIS 57/10010
Date of publication
15 Jul 1956
Number of Pages
30
Reprinted from
Canadian J of Chemistry, vol 34, 1956, p 1611-1640
DSTKIM No
92-03664
CANDIS No
127017
Format(s):
Hardcopy;Originator's fiche received by DSIS

Permanent link

Document 1 of 1

Date modified: