MASS SPECTROMETRIC CHARACTERIZATION OF SULFUR VESICANT HYDROLYSIS PRODUCTS

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Authors
  1. D'Agostino, P.A.
  2. Provost, L.R.
Corporate Authors
Defence Research Establishment Suffield, Ralston ALTA (CAN)
Abstract
Capillary column GC-MS and GC-MS/MS, under EI and ammonia CI conditions, were used to detect and identify longer chain sulfur vesicant hydrolysis products. Interpretation of the MS data enabled the characterization of the partial and fully hydrolysed products of 2-chlorethyl (2-chloroethoxy) ethyl sulfide, sesquimustard and bis[(2-chloroethylthio)ethyl] ether before and after trimethylsilyl derivatization. EI data was generally lacking in significant molecular ion information while that obtained during ammonia CI contained valuable (M+H) (+) and/or (M+NH4) (+) molecular ion information.
Report Number
DRES-586 —
Date of publication
01 Feb 1993
Number of Pages
29
DSTKIM No
93-01493
CANDIS No
129710
Format(s):
Document Image stored on Optical Disk;Originator's fiche received by DSIS

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