t-BUTYLDIMETHYLSILYL DERIVATIVES OF SOME ALKYLPHOSPHONIC AND ALKYL METHYLPHOSPHONIC ACIDS. PART I. GAS CHROMATOGRAPHIC/MASS SPECTROMETRIC STUDIES
- Authors
- Corporate Authors
- Defence Research Establishment Ottawa, Ottawa ONT (CAN)
- Abstract
- Electron impact mass spectra have been generated for t-butyldimethylsilyl derivatives of several alkyl methylphosphonic, alkylphosphonic and halogen-substituted alkylphosphonic acids. In all cases, fragmentation is limited to a few abundant ions indicating that improved quantitation of this class of compounds, essential for verification of chemical arms agreements, will be possible by gas chromatographic/mass spectrometric means using these derivatives. Some fragmentation mechanisms are suggested to account for the major ions of the spectra.
- Report Number
- 910 —
- Date of publication
- 15 Jan 1985
- Number of Pages
- 41
- DSTKIM No
- 85-01333
- CANDIS No
- 46150
- Format(s):
- Hardcopy;Originator's fiche received by DSIS
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