Étude de la Nitration du Triphénylamine: Application à la Stabilité Chimique des Compositions Énergétiques

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Authors
  1. Lussier, L-S.
  2. Désilets, S.
  3. Bergeron, E.
  4. Gagnon, H.
  5. Gagnon, N.
Corporate Authors
Defence R&D Canada - Valcartier, Valcartier QUE (CAN)
Abstract
The products currently used as stabilizers in Canadian Forces munitions produce derivatives that are carcinogenic. Triphenylamine (TPA) is a possible candidate that could be used as a replacement stabilizer for new less toxic energetic materials in the future environmentally friendly munitions. This report discusses the work that has been undertaken in order to acquire the needed tools to push forward the studies on TPA, as a replacement stabilizer. The derivatives that are the most likely to be produced during the ageing of energetic materials stabilized with TPA were identified by using a simple, safe and inexpensive experimental method. Afterward, these derivatives were synthesized and characterized in terms of their appearance and melting point. Finally, data banks containing the UV, IR and NMR spectra were constructed.

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Report Number
DRDC-VALCARTIER-TR-2004-333 — Technical Report
Date of publication
01 Oct 2005
Number of Pages
78
DSTKIM No
CA026459
CANDIS No
524320
Format(s):
CD ROM

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