ELECTRON-SPIN-RESONANCE STUDY OF CHLORINE ATOMS ADSORBED ON A SILICA-GEL SURFACE

Authors
  1. Gardner, C.L.
Corporate Authors
Defence Chemical Biological and Radiation Labs, Ottawa ONT (CAN)
Abstract
An electron-spin-resonance study has been made of chlorine atoms adsorbed on a silica-gel surface at 77K. The experimental results indicate that the orbital degeneracy has been removed as a result of the electrostatic interaction with the surface and is, we believe, the first example of detection of trapped halogen atoms. From the experimental results an estimate of 2.7 X E17 V/square cm has been made for the electric-field gradient at the position of the chlorine atom.
Report Number
DCBRL-523 — Reprint; Previously catalogued as DSIS 67-09589
Date of publication
15 Apr 1967
Number of Pages
4
Reprinted from
Journal of Chemical Physics, vol 46, no 8, 1967, p 2991-2994
DSTKIM No
89-01258
CANDIS No
59190
Format(s):
Hardcopy;Originator's fiche received by DSIS

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