THE SELECTIVE PHOSPHYLATION OF ETHANOLAMINE (paper presented at the 48th meeting of the Chemical Institute of Canada, Montreal, Quebec, 1965)

Authors
  1. Greenhalgh, R.
  2. Weinberger, M.A.
Corporate Authors
Defence Chemical Biological and Radiation Labs, Ottawa ONT (CAN)
Abstract
In nonaqueoous solvents under conditions where phosphylation of either of the functional groups of ethanolamine can occur, it is found that phosphofluoridates react exclusively with the hydroxyl group. This O-phosphylation appears to be specific for phosphofluoridates, since phosphochloridates, tetraethyl pyrophosphate, and ethyl N,N-dimethylphosphoramidocyanidate react predominantly with the amino moiety. However, with these compounds the reaction is not as specific, some O-phosphylation being observed, especially with the last compound. Possible reasons for this difference in behaviour are discussed.
Report Number
DCBRL-513 — Reprint; Previously Catalogued as DSIS 67-03691
Date of publication
01 Jan 1967
Number of Pages
7
Reprinted from
Canadian Journal of Chemistry, vol 45, 1967, p 495-500
DSTKIM No
89-01266
CANDIS No
59198
Format(s):
Hardcopy;Originator's fiche received by DSIS

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