T-BUTYLDIMETHYLSILYL DERIVATIVES OF SOME ALKYLPHOSPHONIC AND ALKYL METHYLPHOSPHONIC ACIDS. PART II. PREPARATION, STABILITY AND QUANTITATIVE ANALYSIS BY GC AND GC/MS

Authors
  1. Purdon, J.G.
  2. Pagotto, J.G.
  3. Miller, R.K.
Corporate Authors
Defence Research Establishment Ottawa, Ottawa ONT (CAN)
Abstract
Studies of t-butyldimethylsilylation of several alkyl methylphosphonic, alkylphosphonic and chlorine-substituted alkylphosphonic acids by several derivatizing reagents under differing reaction conditions are reported and a simple procedure for formation of these derivatives is identified. Determination of the stabilities of representative derivatives are reported and capillary column gas chromatographic (GC) retention data for all the derivatives studied are tabulated. General sensitivities for detection and quantitation of these compounds by Flame Photometric GC and Electron Impact GC/Mass Spectrometry in both full-scan and multiple ion detection modes are presented.
Report Number
DREO-936 —
Date of publication
15 Dec 1985
Number of Pages
24
DSTKIM No
86-03655
CANDIS No
98332
Format(s):
Hardcopy;Originator's fiche received by DSIS

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